Tetra­potassium cis-dioxido-trans-bis­(sulfato-κO)sulfato(κ2 O,O′)molybdate(VI)

نویسندگان

  • Susan J. Cline Schäffer
  • Rolf W. Berg
چکیده

The title compound, K(4)[Mo(VI)O(2)(SO(4))(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [Mo(VI)O(2)(SO(4))(3)](4-) anions, with the Mo(VI) atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane. One of the potassium cations is nine-coordinate, while the other is eight-coordinate.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008